CAS: 1237588-12-3

N-[2-(di-1-adamantylphosphino) phenyl]morpholine, Mor-DalPhos

Synonyms：

N-[2-(di-1-adamantylphosphino) phenyl]morpholine;

Mor-DalPhos;

N-[2-(di-1-adaMantylphosphino)phenyl]Morpholine;

Bis(adamant-1-yl)(2-morpholinophenyl)phosphine;

Di(1-adamantyl)-2-morpholinophenylphosphine;

Bis(1-adamantyl)(2-morpholinophenyl)-phosphine,(Mor-DalPhos);

4-(2-(Di(adamantan-1-yl)phosphino)phenyl)morpholine;

4-[2-[Di(1-Adamantyl)phosphino]phenyl]morpholine;

bis(1-adamantyl)-(2-morpholin-4-ylphenyl)phosphane;

2-Morpholinophenyldi(1-adamantyl)phosphine;

Product Properties:

Melting point: 219-224°C

Storage temp.: 2-8°C

Form: crystal

Sensitive: air sensitive

Reaction:

1.P-N-ligand for use in the Pd-catalyzed cross-coupling of ammonia and hydrazine. Ref. (2) with a diverse range of sterically hindered, unbiased aryl chlorides. Low catalyst loading and mild conditions. Ref (5) with diamines in a chemoselective arylation process. Ref (6) with solvent-free or aqueous conditions.

2.P-N-ligand for the gold-catalyzed stereoselective hydroamination of internal alkynes with dialkylamines to afford E-amines.

3.P-N-ligand for use in the Pd-catalyzed for mono-α-arylation of ketones employing aryl chlorides, bromides, iodides, mesylates (Ref. 7) and tosylates.

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